Lessard Research Group - Next Generation Materials for Next Generation Applications

New Publication on DNA sensors!

P and N type copper phthalocyanines as effective semiconductors in organic thin-film transistor based DNA biosensors at elevated temperatures


Many health-related diagnostics are expensive, time consuming and invasive. Organic thin film transistor (OTFT) based devices show promise to enable rapid, low cost diagnostics that are an important aspect to enabling increased access and availability to healthcare. Here, we describe OTFTs based upon two structurally similar P (copper phthalocyanine – CuPc) and N (hexdecafluoro copper phthalocyanine – F16-CuPc) type semiconductor materials, and demonstrate their potential for use as both temperature and DNA sensors. Bottom gate bottom contact (BGBC) OTFTs with either CuPc or F16-CuPc semiconducting layers were characterized within a temperature range of 25 °C to 90 °C in both air and under vacuum. CuPc devices showed small positive shifts in threshold voltage (VT) in air and significant linear increases in mobility with increasing temperature. F16-CuPc devices showed large negative shifts in VT in air and linear increases in mobility under the same conditions. Similar OTFTs were exposed to DNA in different hybridization states and both series of devices showed positive VT increases upon DNA exposure, with a larger response to single stranded DNA. The N-type F16-CuPc devices showed a much greater sensing response than the P-type CuPc. These findings illustrate the use of these materials, especially the N-type semiconductor, as both temperature and DNA sensors and further elucidate the mechanism of DNA sensing in OTFTs.

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To read the full article visit RSC Adv. website

New Publication in Advanced Electronic Materials!

Polycarbazole-Sorted Semiconducting Single-Walled Carbon Nanotubes for Incorporation into Organic Thin Film Transistors


The realization of organic thin film transistors (OTFTs) with performances that support low-cost and large-area fabrication remains an important and challenging topic of investigation. The unique electrical properties of singlewalled carbon nanotubes (SWNTs) make them promising building blocks for next generation electronic devices. Significant advances in the enrichment of semiconducting SWNTs, particularly via π-conjugated polymers for purification and dispersal, have allowed the preparation of high-performance OTFTs on a small scale. The intimate interaction of the conjugated polymer with both SWNTs and the dielectric necessitates the investigation of avariety of conjugated polymer derivatives for device optimization. Here, the preparation of polymer–SWNT composites containing carbazole moieties, a monomer unit that has remained relatively overlooked for the dispersal of large-diameter semiconducting SWNTs, is reported. This polymer selectively discriminates semiconducting SWNTs using a facile procedure. OTFTs prepared from these supramolecular complexes are ambipolar, and possess superior mobilities and on/off ratios compared to homo poly(fluorene) dispersions, with hole mobilities from random-network devices reaching 21 cm2 V−1 s−1. Atomic force microscopy measurements suggest the poly(carbazole)–SWNT composites form more uniform thin films compared to the poly(fluorene) dispersion. Additionally, treating the silicon dioxide dielectric with octyltrichlorosilane is a simple and effective way to reduce operational hysteresis in SWNT OTFTs.

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To read the full article visit Adv. Elec. Mater. website


Stability of PBDB-T OTFTs! New Publication in J Mater Chem C!

Congrats Sam! The Influence of Air and Temperature on the Performance of PBDB-T and P3HT in Organic Thin Film Transistors


Conjugated polymers such as poly(3-hexylthiophene) (P3HT) are commonly used as semiconducting components in organic photovoltaics (OPVs) and organic thin-film transistors (OTFTs). Such devices may be exposed to oxygen or moisture in air and increased temperature during operation, which can impart consequences on their charge transport properties. Therefore, we produced the first reported example of OTFTs using PBDB-T, a conjugated push-pull polymer used in high performance OPVs, and assessed their performance compared to P3HT under different environmental conditions. Drop casted and annealed bottom-gate, bottom-contact (BGBC) devices had an average mobility of 0.06 cm2/Vs, an on/off current ratio of 104 and a desirable threshold voltage around 0 V. These OTFTs showed distinct responses to characterization at increased temperature in vacuum (P < 0.1 Pa) and air, with PBDB-T devices retaining their performance better than P3HT over time. These findings suggest PBDB-T has higher stability to oxidation when exposed to air than P3HT, especially at high temperatures, and therefore represent a more stable alternative for use in OTFTs and OPVs.

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To read the full article visit J. Mater. Chem C.

SiPc-based OTFTs! New Publication in J. Mater. Chem C!

Silicon Phthalocyanines as N-Type Semiconductors in Organic Thin Film Transistors


Silicon phthalocyanines (SiPcs) represent a large class of molecules that have been studied as donors, acceptors and ternary additives in organic photovoltaics but not in organic thin-film transistors (OTFTs). We synthesized three novel SiPcs using axial substitution and examined their performance as the active layer in bottom-gate bottom-contact (BGBC) OTFTs. All three molecules exhibit N-type behaviour, with the dibenzoate substituted SiPc showing the greatest field-effect mobility of roughly 6 x 10-4 cm2 V-1 s-1 in vacuum. This performance improved to >0.01 cm2 V-1 s-1 when using a combination of dielectric modification with octadecyltrichlorosilane (ODTS) and a substrate temperature during deposition of 200 °C. These promising results point towards the possibility of high performance N-type SiPcs by exploring the wealth of available options in axial and peripheral substitution and careful process control during fabrication.

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To read the full article visit J. Mater. Chem C.

New Publication in Materials!

Organic Thin Film Transistors Incorporating Solution Processable Thieno[3,2-b]thiophene Thienoacenes


Bottom-gate bottom-contact organic thin film transistors (OTFTs) were prepared with four novel star-shaped conjugated molecules containing a fused thieno[3,2-b]thiophene moiety incorporated either in the core and/or at the periphery of the molecular framework. The molecules were soluble in CS2, allowing for solution-processing techniques to be employed. OTFTs with different channel geometries were characterized in both air and vacuum in order to compare environmental effects on performance. Blending the small molecules with poly(styrene), an insulating polymer, facilitated the formation of an even semiconducting film, resulting in an order of magnitude increase in device mobility. The highest field-effect mobilities were in air and on the order of 10−3 cm2/Vs for three of the four molecules, with a maximum mobility of 9.2 × 10−3 cm2/Vs achieved for the most conjugated small molecule. This study explores the relationship between processing conditions and OTFT devices performance for four different molecules within this new family of materials, resulting in a deeper insight into their potential as solution-processable semiconductors.

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To read the full article visit Materials.